Saturday, April 17, 2010

What's New in Release 2010a

Release 2010a includes new features in MATLAB and Simulink, one new product, and updates and bug fixes to 85 other products. Subscribers to MathWorks Software Maintenance Service can download product updates. Beginning with R2010a, PolySpace products require activation. Visit the License Center to download products, activate software, and manage your license and user information.

New capabilities for the MATLAB product family include: New capabilities for the Simulink product family include: Source :
http://www.mathworks.com/products/new_products/latest_features.html

Corrosion - Prediction, Assessment and Material Characterization

Honeywell’s comprehensive set of corrosion software applications facilitates effective decision-making in the fields of corrosion and materials. These software products provide efficient and robust solutions to critical problems in corrosion, cracking and materials selection.

Our software offerings reflect over 20 years of corrosion expertise derived from our laboratory corrosion research benchmarked with actual field data and experience. Plant and consulting engineers have found tremendous value in our software products that aid in materials selection, corrosion rate prediction within pipelines and process equipment, and analysis of plant asset integrity and risk.

Additionally, Honeywell offers software solutions for corrosion prediction in pipelines and production systems, and provides comprehensive services supported by the CorrosionAnalyzer™ modeling framework.

Our corrosion software applications include:

Predict®-SourWater 2.0 - Assessment of corrosion and flow effects. Materials optimization and risk reduction for refinery sour water systems (e.g. REAC, strippers, etc.)

PredictPipe 3.0 - Facilitates Dry Gas Internal Corrosion Direct assessment (DG-ICDA NACE SP0206) for gas transmission pipeline systems.

Predict® 5.0 - Assessment and prediction of corrosion rates for steels exposed to corrosive oil and gas production environments.

Predict®-Amine - Prediction and assessment of corrosion in Rich Amine systems for material selection, increased throughput and process optimization.

Socrates® 9.0 - Provides comprehensive selection of corrosion-resistant alloys (CRA) for oil and gas production environments.

StrategyTM-A 4.0 - Provides assessment of sulfide stress cracking and hydrogen induced cracking in steels, and prioritization of inspection in oil and gas production environments.

StrategyTM-B 4.0 - Provides assessment of sulfide stress cracking and hydrogen induced cracking, and prioritization of inspection in steels in refinery sour water systems.

Risk-ITTM 2.0 - Provides risk and integrity analysis for plant equipment. Evaluates common forms of corrosion degradation.

CorrosionAnalyzer - Provides the ability to thermodynamically simulate and kinetically characterize corrosion in most industrial process environments; including interactions of over 2,000 chemical environments and alloy combinations.


Source : http://hpsweb.honeywell.com/Cultures/en-US/default.htm

Socrates® 9.0

Socrates is a comprehensive material selection tool for oil and gas applications that provides access to the material decision logic of a domain expert, as well as pooled experience and expertise from a distinguished group of operating companies, equipment manufacturers and corrosion resistant alloy (CRA) material suppliers. Socrates enables a methodology for making consistent, optimized material selection choices based on real engineering corrosion data and rigorous materials engineering guidelines.
  • Provides a significant reduction in time spent assessing corrosion using the latest technical data available, which leads to a means for cost-effective automated solutions
  • Provides a cost analysis module facilitating comparison of project cost when using different materials
  • Easy to use graphical interface in a Windows environment makes using Socrates simple and intuitive
  • Incorporates latest NACE MR0175 / ISO15156 CRA Rules for cracking in sour environment
Socrates 9.0 Interface

Socrates 9.0: Multiple Environment/Application Analysis

Socrates 9.0 extends the functionality of Socrates 8.0 with new data, enhanced capabilities and a Microsoft Vista-based interface. Enhancements include:

  • New pH prediction module based on ionic analysis for accurate pH computation
  • Adaptive rules module facilitating modification of system rules to accommodate company-specific data and requirements
  • Extensive new data on the most commonly used CRA materials
  • Integrated selection rules for production environments, as well as acidizing, completion fluids and injected water systems
  • Advanced alloy analysis, including ability to create groups of user-specific alloys
  • Advanced user interface to facilitate concurrent analysis of multiple environments and alloys
  • Enhanced safe use limits module for stainless steel
Source : http://hpsweb.honeywell.com/HPSWebII/SiteNavigator.aspx?Definition=InterCorr

Predict®Pipe 3.0

PredictPipe 3.0 addresses one of the most significant issues in pipeline corrosion evaluation - assessment of corrosion rates in dry gas transmission pipeline systems. These pipelines are exposed to corrosive environments due to water accumulation. The software package is instrumental in enabling easy and accurate Dry Gas ICDA procedures.

PredictPipe 3.0 is a by-product of years of corrosion research and modeling and provides access to a comprehensive knowledge base of corrosion decision-making. It is an easy-to-use graphical tool that integrates the effects of a complex set of environmental parameters to provide a corrosion rate assessment based on extensive literature data, lab testing and field experience.

PredictPipe 3.0: Identification of critical segments

Internal Corrosion Direct Assessment (ICDA)

Gas transmission pipelines under normal operating conditions carry under saturated gas processed by upstream dehydrating units. These pipelines are generally operated with no protection or inhibition and rely on the performance of the dehydrating units to process gas within acceptable standards. It is not unusual for some instability or other process perturbations to result in near saturated gas or some liquid water carryover in such pipelines. These upsets lead to water accumulation in some parts of the pipeline further downstream or cause water condensation due to pressure and temperature changes along the length of the pipeline.

Internal corrosion in pipelines is difficult to locate and measure due to a number of factors. Most internal corrosion detection measures require access to the inside of a pipe for inline inspection and visualization tools such as inline pigs with substantial portions of many pipelines not configured to allow inline inspection.

The ICDA approach to evaluate the likelihood of water accumulation and internal corrosion and identify critical zones, can enhance the actual measurement techniques and ensure safe operation of natural gas pipelines.

One identified by PredictPipe 3.0, a detailed inspection of critical locations where water would most likely accumulate provides the basis that integrity decisions for the remainder of the line can be made. If on inspection no corrosion is found, it is concluded that downstream corrosion is unlikely.

Benefits
  • Using PredictPipe’s Advanced-ICDA technology, users can address internal corrosion in pipelines in a preemptive, proactive basis, and prevent costly failures
  • Advanced-ICDA analysis for gas transmission pipelines through hilly terrain to identify problem zones and view predicted corrosion rate profile throughout the pipeline
  • Determine segment critical angles and identify hot spots where water hold-up can occur
  • Evaluate various glycol injection scenarios and assess effectiveness glycol injection
  • State-of-the-art pH computation module that accounts for the effects of over 16 different anions and cations
  • Ability to accurately model momentum transfer effects (flow regimes, void fractions, pressure drops and shear stresses) en-route to improved corrosion prediction
  • Ability to accurately determine scaling effects due to formation of Iron carbonate and Iron sulfide scales as a function of temperature and pH
  • Ability to accurately characterize role of oxygen concentration in corrosive systems
  • Ability to handle different types of hydrocarbons and persistence effects
  • Updated economic analysis for integrating economic factors into corrosion analysis
Source : http://hpsweb.honeywell.com/HPSWebII/SiteNavigator.aspx?Definition=InterCorr

Predict® 5.0

Predict software is a practical, user-friendly tool to predict corrosion rates of carbon steels in production environments containing CO2 and/or H2S.

Based on user input data, Predict captures the effects of key critical environmental and operating parameters that influence corrosivity and characterizes the effects of these parameters on corrosion rates.

Predict allows a company or site to evaluate the corrosion problem consistently and with high accuracy and repeatability. Predict is built upon a multi-faceted foundation of corrosion knowledge, including hundreds of hours of proprietary, in-house laboratory data, extensive literature information, accurate multiphase flow modeling and the industry’s most comprehensive database on steel corrosion rates.

Predict 5.0 User Interface

Predict® 5.0 is the latest upgrade with new features and Microsoft Vista compatibility. Enhancements include:

  • New predictions for H2S corrosion as a function of wall shear stress
  • New pH prediction module based on ionic analysis
  • Accurately determine scaling effects due to formation of iron carbonate and iron sulfide
  • New Pitting Probability indicator and an advanced pitting corrosion model
  • Evaluation of entire pipeline profiles with horizontal, vertical or inclined segments
  • Advanced flow modeling and correlation to wall shear stress based upon proprietary data from Joint Industry Project (JIP) on multiphase CO2 and H2S corrosion
  • Access to actual test results of corrosion rate data from multiphase flow loop tests
  • Water phase behavior characterization
  • Multi-point and sensitivity analysis support
  • Seamless data exchange with other Honeywell corrosion models
  • Enhanced reporting feature
Source : http://hpsweb.honeywell.com/HPSWebII/SiteNavigator.aspx?Definition=InterCorr

Thursday, April 15, 2010

Cahn-Hilliard Phase Decomposition

Microscale and Nanoscale Applications :
Cahn-Hilliard phase decomposition can model such disparate phenomena as:

* Tin-Lead solder aging
* Void lattice formation in irradiated semiconductors
* Self-assembly of thin film patterns

Free Energy Formulation :
Cahn-Hilliard systems model material separation and interface evolution by racking flow driven by configurational and interfacial free energy minimization.


Cahn-Hilliard Equation :
Adding a material-dependent mobility coefficient defines the concentration flux.



Weak Cahn-Hilliard Equation :
Taking a weighted residual and integrating by parts twice,


Gives a functional defined on in case of constant Mc.

Phase Separation :

* Random perturbations in initial conditions rapidly segregate into two distinct phases, divided by a labyrinth of sharp interfaces.
* Rapid anti-diffusionary process.


Spinodal Decomposition :

* Over long timescales, single-phase regions coalesce.
* Motion into curvature vector resembles surface tension.
* Patterning may occur when additional stress, surface tropisms are applied.


3D Phase Separation :

* Qualitatively similar.
* Topologically very different.
* Much more computationally intensive.

Thin Film Patterning :

* Electrostatic or chemical surface treatment attracts one material component preferentially.
* A spatially varying bias is added to the configurational free energy.

Effects of Bias Strength :
Low surface potential energy biases are overwhelmed by random noise.

Higher surface potential energy biases form patterns with decreasing defect density


Source : www.cfdlab.ae.utexas.edu/~roystgnr/usnccm9.pdf

Wednesday, April 14, 2010

Modelling and Simulation in Materials

Simulation is the imitation of some real thing, state of affairs, or process. The act of simulating something generally entails representing certain key characteristics or behaviours of a selected physical or abstract system.

Simulation is used in many contexts, including the modeling of natural systems or human systems in order to gain insight into their functioning. Other contexts include simulation of technology for performance optimization, safety engineering, testing, training and education. Simulation can be used to show the eventual real effects of alternative conditions and courses of action.

Key issues in simulation include acquisition of valid source information about the relevant selection of key characteristics and behaviours, the use of simplifying approximations and assumptions within the simulation, and fidelity and validity of the simulation outcomes.

A computer simulation (or "sim") is an attempt to model a real-life or hypothetical situation on a computer so that it can be studied to see how the system works. By changing variables, predictions may be made about the behaviour of the system.

Computer simulation has become a useful part of modeling many natural systems in physics, chemistry and biology, and human systems in economics and social science (the computational sociology) as well as in engineering to gain insight into the operation of those systems. A good example of the usefulness of using computers to simulate can be found in the field of network traffic simulation. In such simulations, the model behaviour will change each simulation according to the set of initial parameters assumed for the environment.

Traditionally, the formal modeling of systems has been via a mathematical model, which attempts to find analytical solutions enabling the prediction of the behaviour of the system from a set of parameters and initial conditions. Computer simulation is often used as an adjunct to, or substitution for, modeling systems for which simple closed form analytic solutions are not possible. There are many different types of computer simulation, the common feature they all share is the attempt to generate a sample of representative scenarios for a model in which a complete enumeration of all possible states would be prohibitive or impossible.

Several software packages exist for running computer-based simulation modeling (e.g. Monte Carlo simulation, stochastic modeling, multimethod modeling AnyLogic) that makes the modeling almost effortless.

Modern usage of the term "computer simulation" may encompass virtually any computer-based representation.

Material is synonymous with substance, and is anything made of matter – hydrogen, air and water are all examples of materials. Sometimes the term "material" is used more narrowly to refer to substances or components with certain physical properties that are used as inputs to production or manufacturing. In this sense, materials are the parts required to make something else, from buildings and art to stars and computers.

A material can be anything: a finished product in its own right or an unprocessed raw material. Raw materials are first extracted or harvested from the earth and divided into a form that can be easily transported and stored, then processed to produce semi-finished materials. These can be input into a new cycle of production and finishing processes to create finished materials, ready for distribution, construction, and consumption.

An example of a raw material is cotton, which is harvested from plants. Cotton can be processed into thread (also considered a raw material), which can then be woven into cloth, a semi-finished material. Cutting and sewing the fabric turns it into a garment, which is a finished product. Steelmaking is another example – raw materials in the form of ore are mined, refined and processed into steel, a semi-finished material. Steel is then used as an input in many other industries to make finished products. In chemistry materials can be divided into two metals and non-metals.

Materials science or materials engineering is an interdisciplinary field involving the properties of matter and its applications to various areas of science and engineering. This science investigates the relationship between the structure of materials at atomic or molecular scales and their macroscopic properties. It includes elements of applied physics and chemistry. With significant media attention focused on nanoscience and nanotechnology in recent years, materials science has been propelled to the forefront at many universities. It is also an important part of forensic engineering and failure analysis. The material science also deals with fundamental properties and characteristics of material.

Modelling and Simulation in Materials Science and Engineering is a peer-reviewed scientific journal covering properties, structure and behavior of all classes of materials at scales from the atomic to the macroscopic. This includes electronic structure/properties of materials determined by ab initio and/or semi-empirical methods, atomic level properties of materials, microstructural level phenomena, continuum-level modelling pertaining to material behavior and modelling behavior in service.